cataCXium^® A

ALDRICH/671479 - 95%

Synonym: Di(1-adamantyl)-n-butylphosphine

CAS Number: 321921-71-5
Empirical Formula (Hill Notation): C₂₄H₃₉P
Molecular Weight: 358.54
MDL Number: MFCD05861606
Linear Formula: C₂₄H₃₉P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-671479-1G	1 g	$101.00 1/EA		Add To Favorites
45-671479-5G	5 g	$399.00 1/EA		Add To Favorites
45-671479-50G	50 g	$3790.00 1/EA		Add To Favorites
45-671479-100G	100 g	$5650.00 1/EA		Add To Favorites
45-671479-250G	250 g	$13140.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
functional group	phosphine
InChI	1S/C24H39P/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24/h17-22H,2-16H2,1H3/t17-,18+,19-,20-,21+,22-,23-,24-
InChI key	HTJWUNNIRKDDIV-FECFBMJZSA-N
Quality Level	100
reaction suitability	reagent type: ligand reaction type: Arylations
	reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reagent type: ligand reaction type: C-C Bond Formation
	reagent type: ligand reaction type: Cross Couplings
	reagent type: ligand reaction type: Heck Reaction
	reagent type: ligand reaction type: Sonogashira Coupling
	reagent type: ligand reaction type: Suzuki-Miyaura Coupling
SMILES string	CCCCP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@@]45C[C@@H]6C[C@@H](C[C@@H](C6)C4)C5

Application:	cataCXium^® A or di-adamantylalkylphosphine is a bulky and electron-rich phosphine ligand that is highly effective for palladium catalyzed cross-coupling reactions such as Heck and Suzuki coupling, Buchwald-Hartwig amination of aryl chlorides, and α-arylation reactions of ketones. Other applications: • palladium-catalyzed carbonylation of aryl and heteroaryl halides • palladium-catalyzed synthesis of (hetero)aromatic nitriles • palladium-catalyzed aminocarbonylation of aryl halides
Features and Benefits:	• Mild reaction condition • Low catalyst loading • High yield and turn over number
General description:	Sold in collaboration with Solvias AG cataCXium^® A is commonly used as a catalyst in cross-coupling reactions, such as Suzuki and Sonogashira reactions.
Legal Information:	cataCXium is a registered trademark of Umicore AG & Co. KG
Legal Information:	US7148176
Packaging:	1, 5 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95%
UNSPSC	12352001

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