2-Benzyloxyphenylmagnesium bromide solution

ALDRICH/673013 - 1.0 M in THF

CAS Number: 328000-16-4
Empirical Formula (Hill Notation): C₁₃H₁₁BrMgO
Molecular Weight: 287.43
MDL Number: MFCD08705262
Linear Formula: C₁₃H₁₁BrMgO
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-673013-50ML	50 mL	$318.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
density	1.047 g/mL at 25 °C
InChI	1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1
InChI key	VELKJPFZDYXBDE-UHFFFAOYSA-M
Quality Level	100
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]c1ccccc1OCc2ccccc2

Application:	2-Benzyloxyphenylmagnesium bromide can be used: • As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols. • As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride. • In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.
Packaging:	50 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
Hazard Codes	F,C
Risk Statements	11-14-19-34-37-40
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-4.0 - 5.0 °F - closed cup
Flash Point(C)	-20 - -15 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	1.047 g/mL at 25 °C
UNSPSC	12352103

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