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Pentamethylcyclopentadienylbis(triphenylphosphine)ruthenium(II) chloride

ALDRICH/673293

Synonym: Cp*RuCl(PPh3)2; Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II)

CAS Number: 92361-49-4
Empirical Formula (Hill Notation): C46H45ClP2Ru
Molecular Weight: 796.32
MDL Number: MFCD09038426
Linear Formula: [(C10H15)Ru(P((C6H5)3))2Cl]
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-673293-250MG 250 mg
 $122.00
1/EA		 Add To Favorites
45-673293-1G 1 g
 $288.00
1/EA		 Add To Favorites

 

form solid
InChI 1S/2C18H15P.C10H15.ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-6-7(2)9(4)10(5)8(6)3;;/h2*1-15H;1-5H3;1H;/q;;;;+1/p-1
InChI key KLXKSZDVKAWYRT-UHFFFAOYSA-M
mp 128 °C (D)
reaction suitability core: ruthenium
  reagent type: catalyst
reaction type: click chemistry
SMILES string Cl[Ru].C[C]1[C](C)[C](C)[C](C)[C]1C.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7
storage temp. 2-8°C
Application: Catalyst employed in the cycloaddtion of azides with acetylenes giving exclusively the 1,5-disubstitutedtriazoles in contrast to the 1,4-regiochemistry commonly observed with copper catalysis. Ruthenium catalysis also enables the use of internal acetylenes in these "click cycloaddtions".
Application: Versatile catalyst for living radical polymerization
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 128 °C (D)
Storage Temp. 2-8°C
UNSPSC 12161600

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