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2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine

ALDRICH/673978

Synonym: (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole; (3aS,8aR)-in-pybox

CAS Number: 185346-09-2
Empirical Formula (Hill Notation): C25H19N3O2
Molecular Weight: 393.44
MDL Number: MFCD05861599
Linear Formula: C25H19N3O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-673978-250MG 250 mg
 $143.00
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45-673978-1G 1 g
 $0.00
1/EA
CALL FOR PRICE		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 673978-250MG.

 

form solid
InChI 1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1
InChI key BZSJUFJXCHHRHW-LUKWVAJMSA-N
mp 276-281 °C
optical activity [α]20/D -375°, c = 1 in dichloromethane (typical)
SMILES string C1[C@H]2OC(=N[C@H]2c3ccccc13)c4cccc(n4)C5=N[C@@H]6[C@@H](Cc7ccccc67)O5
Application: Reactant involved in synthesis of:
• Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
• Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
• Chiral N,N,N-tridentate pybos and pyboxazine ligands
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass insert
Hazard statements H413
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 276-281 °C
UNSPSC 12352005

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