2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
ALDRICH/673986 - ≥94%
Synonym: (3aR,3′aR,8aS,8′aS)-2,2′-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole; (3aR,8aS)-in-pybox
CAS Number: 357209-32-6
Empirical Formula (Hill Notation): C25H19N3O2
Molecular Weight: 393.44
MDL Number: MFCD09265074
Linear Formula: C25H19N3O2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 673986-1G
| assay | ≥94% |
| form | solid |
| functional group | ether |
| InChI | 1S/C25H19N3O2/c1-3-8-16-1 |
| InChI key | BZSJUFJXCHHRHW-MYDTUXCISA |
| mp | 284 °C (dec.) |
| optical activity | [α]20/D +386°, c = 1 in methylene chloride(lit.) |
| Quality Level | 200  |
| SMILES string | C1[C@@H]2OC(=N[C@@H]2c3cc |
| Application: | Catalytic ligand used for: • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage • Enantioselective Mukaiyama-aldol reactions • Enantioselective carbonyl-ene reactions • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex • Enantioselective Diels-Alder reaction • Ni-catalyzed cross-coupling reactions |
| Packaging: | 1 g in glass bottle |
| Packaging: | 250 mg in glass bottle |
| Hazard statements | H413 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥94% |
| mp | 284 °C (dec.) |
| UNSPSC | 12352005 |