Synonym: (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1′,2′f]-1,3,2-dioxaphosphepin 4-oxide; MacMillan TiPSY catalyst
CAS Number: 791616-55-2
Empirical Formula (Hill Notation): C56H41O4PSi2
Molecular Weight: 865.07
MDL Number: MFCD09265079
Linear Formula: C56H41O4PSi2
Product Type: Chemical
assay |
95% |
form |
solid |
InChI |
1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58) |
InChI key |
BDQOCXQVIFQJRK-UHFFFAOYSA-N |
mp |
329-335 °C |
optical activity |
[α]22/D -197°, c = 1 in chloroform |
SMILES string |
OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11 |
Application: |
Organocatalyst for the first enatioselective organocatalytic reductive amination reaction. |
Packaging: |
100 mg in clear glass bottle |
Purity |
95% |
mp |
329-335 °C |
UNSPSC |
12352005 |