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(R)-(–)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

ALDRICH/674745 - 95%

Synonym: (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1′,2′f]-1,3,2-dioxaphosphepin 4-oxide; MacMillan TiPSY catalyst

CAS Number: 791616-55-2
Empirical Formula (Hill Notation): C56H41O4PSi2
Molecular Weight: 865.07
MDL Number: MFCD09265079
Linear Formula: C56H41O4PSi2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-674745-100MG 100 mg
 $470.00
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assay 95%
form solid
functional group phosphate
InChI 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
InChI key BDQOCXQVIFQJRK-UHFFFAOYSA-N
mp 329-335 °C
optical activity [α]22/D -197°, c = 1 in chloroform
Quality Level 100 
SMILES string OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
Application: Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.
Packaging: 100 mg in clear glass bottle
Purity 95%
mp 329-335 °C
UNSPSC 12352005

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