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(S)-VANOL

ALDRICH/676098 - 97%

Synonym: (S)-3,3′-Diphenyl-2,2′-bi(1-naphthalol); (S)-3,3′-Diphenyl-2,2′-bi-(1-naphthol)

CAS Number: 147702-14-5
Empirical Formula (Hill Notation): C32H22O2
Molecular Weight: 438.52
MDL Number: MFCD08459338
Linear Formula: C32H22O2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-676098-250MG 250 mg
 $164.00
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assay 97%
InChI 1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
InChI key NDTDVKKGYBULHF-UHFFFAOYSA-N
mp 199-203 °C
optical activity [α]20/D -314°, c = 1 in chloroform
SMILES string Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
Application: (S)-VANOL is a vaulted biaryl ligand that may be used in the synthesis of coordinated complexes, such as (dppe)Pt(S-VANOL) [dppe= bis(diphenylphosphino)ethane] and (S,S-chiraphos)Pt(S-VANOL) [chiraphos= 2,3-bis(diphenylphosphino)butane].
Application: VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
Packaging: 250 mg in amber glass bottle
Purity 97%
mp 199-203 °C
UNSPSC 12352005

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