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APhos

ALDRICH/677264 - 95%

Synonym: (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine; A-taPhos; [4-(Dimethylamino)phenyl]bis(tert-butyl)phosphine

CAS Number: 932710-63-9
Empirical Formula (Hill Notation): C16H28NP
Molecular Weight: 265.37
MDL Number: MFCD09265102
Linear Formula: C16H28NP
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-677264-1G 1 g
 $80.10
1/EA		 Add To Favorites
45-677264-5G 5 g
 $203.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 677264-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 677264-5G

 

assay 95%
form solid
functional group phosphine
InChI 1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3
InChI key IQTHEAQKKVAXGV-UHFFFAOYSA-N
mp 57-61 °C
Quality Level 100 
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
  reagent type: ligand
reaction type: Cross Couplings
SMILES string CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C
Application: Ligand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.
Packaging: 1, 5 g in glass bottle
Symbol GHS05  GHS05
Signal word Danger
Hazard statements H314
Precautionary statements P280 - P305 + P351 + P338 - P310
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 57-61 °C
UNSPSC 12352116

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