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[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct

ALDRICH/677922

Synonym: [Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct

Empirical Formula (Hill Notation): C47H38Au2F12N2O8P2S4
Molecular Weight: 1570.93
MDL Number: MFCD09038445
Linear Formula: (C20H15AuF6NO4PS2) 2 · C7H8
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-677922-250MG 250 mg
 $151.00
1/EA		 Add To Favorites
45-677922-1G 1 g
 $405.00
1/EA		 Add To Favorites

 

form solid
InChI 1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1
InChI key SIVCTOVPPFSWEF-UHFFFAOYSA-N
Quality Level 100 
reaction suitability core: gold
  reagent type: catalyst
SMILES string [Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
Application: Gold Catalysts — 21st Century ′Gold Rush′ 
Application: [Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct can be used as a catalyst in the 1,3-isomerisation of propargylic alcohols to enones via Meyer-Schuster rearrangement.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
UNSPSC 12161600

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