(+)-Ipc₂B(allyl)borane solution

ALDRICH/678503 - 1 M in pentane

Synonym: (+)-Ipc₂B(allyl) solution; (+)-B-Allyldiisopinocampheylborane solution

CAS Number: 106356-53-0
Empirical Formula (Hill Notation): C₂₃H₃₉B
Molecular Weight: 326.37
Linear Formula: (C₁₀H₁₇)₂BCH₂CH=CH₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-678503-5ML	5 mL	$90.10 1/EA		Add To Favorites
45-678503-25ML	25 mL	$335.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

bp	35-36 °C
concentration	1 M in pentane
density	0.735 g/mL at 25 °C
InChI	1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m0/s1
InChI key	ZIXZBDJFGUIKJS-AXSQLCHVSA-N
optical activity	[α]20/D +14°, c = 1 in pentane
Quality Level	100
SMILES string	C[C@@H]1[C@H](C[C@H]2C[C@@H]1C2(C)C)B(CC=C)[C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C
storage temp.	−20°C

Application:	This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.
General description:	http://www.sigmaaldrich.com/ifb/acta/v35/acta-vol35-2002.html#32
Other Notes:	Material may become hazy upon cooler storage, this will not affect use
Other Notes:	Under refrigerator storage, these salt-free, Ipc₂B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.
Packaging:	5, 25 mL in ampule

Symbol	GHS02,GHS07,GHS08,GHS09
Signal word	Danger
Hazard statements	H224 - H304 - H315 - H319 - H335 - H336 - H411
Precautionary statements	P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233
Hazard Codes	F,Xn,N
Risk Statements	11-36/37/38-51/53-65-67
Safety Statements	16-26-61-62
RIDADR	UN1265 - class 3 - PG 2 - Pentanes solution
WGK Germany	WGK 3
Flash Point(F)	-56.2 °F
Flash Point(C)	-49 °C

bp	35-36 °C
Density	0.735 g/mL at 25 °C
Storage Temp.	−20°C
UNSPSC	12352002

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