Di-(4-chlorobenzyl)azodicarboxylate

ALDRICH/680850 - 97%

Synonym: Bis(4-chlorobenzyl)azodicarboxylate; DCAD

CAS Number: 916320-82-6
Empirical Formula (Hill Notation): C₁₆H₁₂Cl₂N₂O₄
Molecular Weight: 367.18
MDL Number: MFCD27995640
Linear Formula: C₁₆H₁₂Cl₂N₂O₄
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-680850-1G	1 g	$80.90 1/EA	Add To Favorites
45-680850-10G	10 g	$704.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 680850-1G

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	solid
functional group	azo
	chloro
InChI	1S/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2/b20-19-
InChI key	UIFGGABIJBWRMG-VXPUYCOJSA-N
mp	108-112 °C
Quality Level	200
SMILES string	O=C(/N=NC(OCC1=CC=C(Cl)C=C1)=O)OCC2=CC=C(Cl)C=C2

Application:	Di-(4-chlorobenzyl)azodicarboxylate (DCAD) is a novel, stable, solid alternative to DEAD and DIAD for a variety of Mitsunobu couplings giving a readily separable hydrazine byproduct that can be recycled.
Application:	Reactant for preparation of: • Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters • Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium • DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions
General description:	Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.
Packaging:	1, 10 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H317
Precautionary statements	P280
Hazard Codes	Xi
Risk Statements	43
Safety Statements	36/37
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	108-112 °C
UNSPSC	12352101

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