1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene

ALDRICH/680990

Synonym: R,R-Et-Ferrocelane^™

CAS Number: 147762-89-8
Empirical Formula (Hill Notation): C₂₆H₄₀FeP₂
Molecular Weight: 470.39
MDL Number: MFCD09265149
Linear Formula: C₂₆H₄₀FeP₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-680990-100MG	100 mg	$140.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
functional group	phosphine
InChI	1S/2C13H25P.2CH3.Fe/c21-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h211-13H,3-10H2,1-2H3;21H3;/t211-,12-;;;/m11.../s1
InChI key	CPUKIDAUDCWIRT-QULUYMGFSA-N
mp	85-91 °C
optical activity	[α]20/D +380°, c = 1 in chloroform
Quality Level	100
SMILES string	C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4

Application:	1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used: • As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones. • As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.
Application:	DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Legal Information:	Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.
Legal Information:	Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Packaging:	100, 500 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	85-91 °C
UNSPSC	12352005

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