Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
ALDRICH/682101
Synonym: Bis(trimethylaluminum)
CAS Number: 137203-34-0
Empirical Formula (Hill Notation): C12H30Al2N2
Molecular Weight: 256.34
MDL Number: MFCD09265160
Linear Formula: (CH3)3Al · C6H12N2 · Al(CH3)3
Product Type: Chemical
InChI | 1S/C6H12N2.6CH3.2Al/c1-2- |
InChI key | WSTAITCRSVOCTK-UHFFFAOYSA |
mp | >250 °C |
Quality Level | 100 |
SMILES string | C[Al-](C)(C)[N+]12CC[N+]( |
Application: | DABAL-Me3: An Air Stable "Methyl Anion" |
Application: | A more stable alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation. |
General description: | Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere. |
Legal Information: | DABCO is a registered trademark of Air Products & Chemicals, Inc. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS02,GHS07 |
Signal word | Danger |
Hazard statements | H260 - H302 - H315 - H319 - H335 |
Precautionary statements | P231 + P232 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | F,Xn |
Risk Statements | 14-15-22-36/37/38 |
Safety Statements | 16-26-43 |
RIDADR | UN 3395 4.3 / PGI |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Supplemental Hazard Statements | EUH014 |
mp | >250 °C |
UNSPSC | 12352103 |