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(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine

ALDRICH/682322 - ≥96%

Synonym: (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene; Methyl-BoPhoz

CAS Number: 406680-94-2
Empirical Formula (Hill Notation): C37H35FeNP2
Molecular Weight: 611.47
MDL Number: MFCD05865220
Linear Formula: C37H35FeNP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-682322-500MG 500 mg
 $261.00
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assay ≥96%
form solid
functional group amine
  phosphine
InChI 1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
InChI key ZIAZHUWEJYUGEO-FBHGDYMESA-N
mp 108.7-113.6 °C
Quality Level 100 
SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
Application: (R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.
Application: Efficient ligand for asymmetric hydrogenation
Legal Information: Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.
Packaging: 100 mg in clear glass bottle
Packaging: 500 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥96%
mp 108.7-113.6 °C
UNSPSC 12352005

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