Grubbs Catalyst^® M360

ALDRICH/682381

Synonym: Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][3-(2-pyridinyl) propylidene]ruthenium(II); Grubbs Catalyst^® C598; [1,3-Dimesityl-2-imidazolidinylidene]dichloro[3-(2-pyridinyl)propylidene]ruthenium(II)

CAS Number: 802912-44-3
Empirical Formula (Hill Notation): C₂₉H₃₅Cl₂N₃Ru
Molecular Weight: 597.58
Linear Formula: C₂₉H₃₅Cl₂N₃Ru
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-682381-100MG	100 mg	$117.00 1/EA	Add To Favorites
45-682381-500MG	500 mg	$442.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

InChI	1S/C21H27N2.C8H9N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-5-8-6-3-4-7-9-8;;;/h9-13H,7-8H2,1-6H3;1,3-4,6-7H,2,5H2;2*1H;/q;;;;+2/p-2
InChI key	LCRADYBTPYSTNK-UHFFFAOYSA-L
mp	190.5-199.0 °C
Quality Level	100
SMILES string	Cc1cc(C)c(N2CCN(C2[Ru](Cl)(Cl)=CCCc3ccccn3)c4c(C)cc(C)cc4C)c(C)c1
storage temp.	2-8°C

Application:	• Latent initiator, but extremely active once initiated, similar to other 2^nd generation catalysts. • Useful in ROMP applications where longer monomer/catalyst resin handling times are desired. • Potentially useful in non-ROMP applications as well. • Enabling metathesis catalyst.
Application:	Metathesis: Ruthenium-Based Metathesis Catalysts • Catalyst for olefin metathesis reactions
Legal Information:	Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG
Legal Information:	Product of Umicore Product License This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer’s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein. For any further information on product please refer to your local Umicore PMC contact at www.pmc.umicore.com.
Packaging:	100, 500 mg in glass bottle
Packaging:	2 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	190.5-199.0 °C
Storage Temp.	2-8°C
UNSPSC	12352300

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