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Chiralyst P461

ALDRICH/683167 - Umicore

Synonym: Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer; Di(μ-chloro)bis(norbornadiene)dirhodium(I); 2,5-Norbornadiene-rhodium(I) chloride dimer; Chloro(2,5-norbornadiene)rhodium(I) dimer; Rhodium(I) chloride 2,5-Norbornadiene complex dimer; [Rh(nbd)Cl]2

CAS Number: 12257-42-0
Empirical Formula (Hill Notation): C14H16Cl2Rh2
Molecular Weight: 460.99
EC Number: 235-510-4
MDL Number: MFCD00198060
Linear Formula: C14H16Cl2Rh2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-683167-500MG 500 mg
$335.00
1/EA
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45-683167-2G 2 g
$647.00
1/EA
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form powder
InChI 1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;
InChI key RXDWVIOULPVOEO-SEGRDSFWSA-L
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4
Application: Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis 

Hydrosilylation Catalysts 
Application: Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation
Legal Information: Product of Umicore

Additional information available at www.pmc.umicore.com 
Packaging: 2 g in glass bottle
Packaging: 500 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
UNSPSC 12352300

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