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Chiralyst P374

ALDRICH/683175 - Umicore

Synonym: Bis(norbornadiene)rhodium(I) tetrafluoroborate; Bis(bicyclo[2.2.1]hepta-2,5-diene)rhodium tetrafluoroborate; Bis(norbornadiene)(tetrafluoroborato)rhodium; Rh(nbd)2BF4; Rh(nbd)2BF4

CAS Number: 36620-11-8
Empirical Formula (Hill Notation): C14H16BF4Rh
Molecular Weight: 373.99
MDL Number: MFCD00671775
Linear Formula: [Rh(NBD)BF4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-683175-500MG 500 mg
 $235.00
1/EA		 Add To Favorites
45-683175-2G 2 g
 $912.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 683175-2G

 

form solid
InChI 1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;
InChI key HAYDJWBQWOEERB-JAGGYEKFSA-N
mp 136.9-139.9 °C
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string [Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4
Application: Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis 
Application: Bis(norbornadiene)rhodium(I) tetrafluoroborate can be used as a catalyst for the synthesis of:
• Lactones via the 1,4-addition of arylboronic acids to butenolide.
• Chiral β-aryl-substituted ketones and esters.
• β-aryloxycarboxylic esters from β-aryloxy-α,γ-unsaturated esters.
Legal Information: Product of Umicore

Additional information available at www.pmc.umicore.com 
Packaging: 2 g in poly bottle
Packaging: 500 mg in poly bottle
mp 136.9-139.9 °C
UNSPSC 12352300

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