(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine

ALDRICH/683248

CAS Number: 913617-04-6
Empirical Formula (Hill Notation): C₄₆H₃₆NO₂P₃
Molecular Weight: 727.70
MDL Number: MFCD09750461
Linear Formula: C₄₆H₃₆NO₂P₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-683248-500MG	500 mg	$284.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
functional group	amine
	phosphine
InChI	1S/C46H36NO2P3/c1-47(2)52-48-45-41(50(35-21-7-3-8-22-35)36-23-9-4-10-24-36)31-33-19-15-17-29-39(33)43(45)44-40-30-18-16-20-34(40)32-42(46(44)49-52)51(37-25-11-5-12-26-37)38-27-13-6-14-28-38/h3-32H,1-2H3
InChI key	JVTXDRKUFXCFCF-UHFFFAOYSA-N
mp	245-249 °C
Quality Level	100
SMILES string	CN(C)P1Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)P(c6ccccc6)c7ccccc7)P(c8ccccc8)c9ccccc9
storage temp.	2-8°C

Application:	(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine is a phosphine-phosphoramidite ligand, which can be used in: • The stereoselective preparation of aminoesters via rhodium-catalyzed enantioselective hydrogenation of dehydroaminoesters. • The Rh-catalyzed asymmetric hydrogenation of N-(α-arylvinyl) acetamides.
Application:	DSM MonoPhos Family of Highly Efficient Privileged Ligands
Legal Information:	Sold under license from DSM for research purposes only.
Packaging:	100 mg in clear glass bottle
Packaging:	500 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	245-249 °C
Storage Temp.	2-8°C
UNSPSC	12352005

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