[Pd(allyl)Cl]2
ALDRICH/683396 - Umicore
Synonym: Allylpalladium(II) chloride dimer; Allylchloropalladium dimer; Bis(η3-allyl)di(μ-chloro)dipalladium(II); Bis(allyl)
CAS Number: 12012-95-2
Empirical Formula (Hill Notation): C6H10Cl2Pd2
Molecular Weight: 365.89
EC Number: 234-579-8
MDL Number: MFCD00044874
Linear Formula: C6H10Cl2Pd2
Product Type: Chemical
assay | ≥98.0% (C, elemental analysis) |
form | solid |
InChI | 1S/2C3H5.2ClH.2Pd/c2*1-3- |
InChI key | TWKVUTXHANJYGH-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | core: palladium |
reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
reaction type: Cross Couplings | |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst | |
SMILES string | Cl[Pd]CC=C.Cl[Pd]CC=C |
storage temp. | 2-8°C |
Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
Application: | [Pd(allyl)Cl]2 can be used as a catalyst: • For the silylation of organobromides. • To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides. • To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization. |
Legal Information: | Product of Umicore Additional information available at www.pmc.umicore.com |
Other Notes: | Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis |
Packaging: | 5 g in glass bottle |
Packaging: | 500 mg in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 |
Precautionary statements | P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Purity | ≥98.0% (C, elemental analysis) |
Storage Temp. | 2-8°C |
UNSPSC | 12352300 |