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[Pd(allyl)Cl]2

ALDRICH/683396 - Umicore

Synonym: Allylpalladium(II) chloride dimer; Allylchloropalladium dimer; Bis(η3-allyl)di(μ-chloro)dipalladium(II); Bis(allyl)dichlorodipalladium; Bis(allyl)dichloropalladium; Bis(allylchloropalladium); Diallyldichlorodipalladium; [PdCl(C3H5)]2

CAS Number: 12012-95-2
Empirical Formula (Hill Notation): C6H10Cl2Pd2
Molecular Weight: 365.89
EC Number: 234-579-8
MDL Number: MFCD00044874
Linear Formula: C6H10Cl2Pd2
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-683396-500MG 500 mg
$88.40
1/EA
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45-683396-5G 5 g
$778.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 683396-500MG

 

assay ≥98.0% (C, elemental analysis)
form solid
InChI 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChI key TWKVUTXHANJYGH-UHFFFAOYSA-L
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string Cl[Pd]CC=C.Cl[Pd]CC=C
storage temp. 2-8°C
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: [Pd(allyl)Cl]2 can be used as a catalyst:
• For the silylation of organobromides.
• To synthesize α-aryl carbonyl compounds by coupling reaction between aldehydes and aryl halides.
• To prepare various arylthiophene derivatives by cross-coupling reaction with aryl halides via C-H functionalization.

Legal Information: Product of Umicore

Additional information available at www.pmc.umicore.com 
Other Notes: Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis 
Packaging: 5 g in glass bottle
Packaging: 500 mg in glass bottle
Purity ≥98.0% (C, elemental analysis)
Storage Temp. 2-8°C
UNSPSC 12352300

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