1,2-Bis(phenylsulfinyl)ethane palladium(II) acetate

ALDRICH/684821

Synonym: White catalyst

CAS Number: 858971-43-4
Empirical Formula (Hill Notation): C₁₈H₂₀O₆PdS₂
Molecular Weight: 502.90
MDL Number: MFCD09842752
Linear Formula: C₁₈H₂₀O₆PdS₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-684821-250MG	250 mg	$0.00 1/EA CALL FOR PRICE	Add To Favorites
45-684821-1G	1 g	$137.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 684821-1G

12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

Properties
Descriptions
Safety Info.
Basic Data

form	powder
greener alternative category	Aligned ,
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/C14H14O2S2.2C2H4O2.Pd/c15-17(13-7-3-1-4-8-13)11-12-18(16)14-9-5-2-6-10-14;21-2(3)4;/h1-10H,11-12H2;21H3,(H,3,4);/q;;;+2/p-2
InChI key	SNNYSJNYZJXIFE-UHFFFAOYSA-L
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: C-H Activation
SMILES string	CC(=O)O[Pd]OC(C)=O.O=S(CCS(=O)c1ccccc1)c2ccccc2
storage temp.	−20°C
sustainability	Greener Alternative Product

Application:	White Catalyst: A Catalyst for Allylic C–H Oxidation and Amination
Application:	Macrolactonization via Hydrocarbon Oxidation
Application:	Catalyst for allylic C-H oxidation, useful for preparation of branched allylic esters, macrocycles, and amino alcohol derivatives.
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS05
Signal word	Danger
Hazard statements	H318
Precautionary statements	P280 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	41
Safety Statements	26-39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Storage Temp.	−20°C
UNSPSC	12161600

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