(1,5-Cyclooctadiene)(methoxy)iridium(I) dimer
ALDRICH/685062
Synonym: [Ir(OMe)(1,5-cod)]2; Bis(1,5-
CAS Number: 12148-71-9
Empirical Formula (Hill Notation): C18H30Ir2O2
Molecular Weight: 662.86
MDL Number: MFCD08459360
Linear Formula: [Ir(OCH3)(C8H12)]2
Product Type: Chemical
form | crystals |
InChI | 1S/2C8H12.2CH3O.2Ir/c2*1- |
InChI key | BGWIAAATAAWGOI-MIXQCLKLSA |
mp | 154-179 °C (D) |
Quality Level | 100 |
reaction suitability | core: iridium |
reagent type: catalyst reaction type: C-H Activation |
|
SMILES string | C[O+]1[Ir-]2[O+](C)[Ir-]1 |
storage temp. | −20°C |
Application: | A powerful C-H activation catalyst to prepare phenols from arenes |
Application: | Catalyst for: • Preparation of heteroaryl fused indole ring systems as inhibitors of HCV NS5B polymerase • Borylation/Suzuki-Miyau • Metalation-Suzuki cross-coupling procedure for the synthesis of biaryls and heterobiaryls • Tetraborylation reactions • Highly regio- and enantioselective asymmetric hydroboration • Ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation |
Packaging: | 1, 25 g in glass bottle |
Packaging: | 250 mg in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 154-179 °C (D) |
Storage Temp. | −20°C |
UNSPSC | 12161600 |