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Chiralyst P618

ALDRICH/686891 - Umicore

Synonym: Pentamethylcyclopentadienylrhodium(III) chloride dimer; Di(μ-chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III); 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex; Bis(dichloro(pentamethylcyclopentadienyl)rhodium); Bis(pentamethylcyclopentadienylrhodium dichloride); Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer; Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

CAS Number: 12354-85-7
Empirical Formula (Hill Notation): C20H30Cl4Rh2
Molecular Weight: 618.08
MDL Number: MFCD00061552
Linear Formula: [Rh(C5Me5)Cl2]2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-686891-500MG 500 mg
 $393.00
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45-686891-2G 2 g
 $1110.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 686891-2G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 686891-500MG

 

form powder
InChI 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
InChI key QNIVKTTWBMFSBR-UHFFFAOYSA-J
Quality Level 100 
reaction suitability core: rhodium
  reaction type: Cross Couplings
  reagent type: catalyst
reaction type: C-H Activation
SMILES string Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
Application: Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis 

Catalyst for:
• Oxidative olefination reactions
• C-C bond cleavage of secondary alcohols
• Ortho C-H olefination of phenol derivatives
• Oxidative annulation of pyridines
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond
• Amidation reactions
• Reductive alkylation reactions
Application: Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:
•  The synthesis of multiaryl substituted naphthols via dual C-H bond functionalization of 2-aryloxypyridines.
•  Regioselective C-N bond formation of azo compounds, wherein azide acts as a nitrogen source.
•  Annulation of N-benzoylsulfonamide with isocyanide via C-H bond activation.
Legal Information: Product of Umicore

Additional information available at www.pmc.umicore.com 
Packaging: 2 g in glass bottle
Packaging: 500 mg in glass bottle
UNSPSC 12161600

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