Tris[2-phenylpyridinato-C2,N]iridium(III)
ALDRICH/688096 - 97%
Synonym: Ir(ppy)3; Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
CAS Number: 94928-86-6
Empirical Formula (Hill Notation): C33H24IrN3
Molecular Weight: 654.78
MDL Number: MFCD12022527
Linear Formula: C33H24IrN3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 688096-250MG
| assay | 97% |
| description | fac-Tris[2-phenylpyridinato- |
| fluorescence | λex 340 nm; λem 512 nm in chloroform |
| form | powder |
| InChI | 1S/3C11H8N.Ir/c3*1-2-6-10 |
| InChI key | QKBWDYLFYVXTGE-UHFFFAOYSA |
| OLED device performance | ITO/HMPD/TAZ:Ir(ppy)3 (7%)/Alq3/Al:Li • Color: green • Max. Luminance: 4000 Cd/m2 • Max. EQE: 15 % |
| ITO/NPD/CBP:Ir(ppy)3 (6%)/Alq3/Mg:Ag • Color: green • Max. Luminance: 100000 Cd/m2 • Max. EQE: 8 % • Turn-On Voltage: 4.3 V |
|
| ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al • Color: green • Max. Luminance: 207839 Cd/m2 • Max. EQE: 21.6 % • Turn-On Voltage: 2.1 V |
|
| ITO/TCTA/Ir(ppy)3/Bphen/LiF/Al • Color: green • Max. Luminance: 300000 Cd/m2 • Max. EQE: 19 % • Turn-On Voltage: 2.6 V |
|
| orbital energy | HOMO 5.6 eV |
| LUMO 3 eV | |
| photocatalyst activation | 425 nm |
| reaction suitability | core: iridium |
| reaction type: Photocatalysis | |
| reagent type: catalyst | |
| SMILES string | c1ccc(nc1)-c2ccccc2[Ir](c |
| Application: | Learn More at the Professor and Product Portal of Professor Corey Stephenson  . |
| Application: | Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were also achieved with this catalyst. Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions  Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 ) |
| General description: | Tris-(2-phenylpyridine) iridium [Ir(ppy)3] is a heavy metal complex. [Ir(ppy)3] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity. |
| Packaging: | 250 mg in glass insert |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| UNSPSC | 12352103 |