(S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

ALDRICH/689785 - ≥97.0% (qNMR)

Synonym: (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide; (S)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-bi-2-naphthol cyclic monophosphate; (S)-TRIP

CAS Number: 874948-63-7
Empirical Formula (Hill Notation): C₅₀H₅₇O₄P
Molecular Weight: 752.96
MDL Number: MFCD10567009
Linear Formula: C₅₀H₅₇O₄P
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-689785-100MG	100 mg	$589.00 1/EA	Add To Favorites
45-689785-500MG	500 mg	$1420.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 689785-500MG.

12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

Properties
Descriptions
Safety Info.
Basic Data

assay	≥97.0% (qNMR)
form	lumps
greener alternative category	, Aligned
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/C50H57O4P/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12/h13-32H,1-12H3,(H,51,52)
InChI key	AGQAQYPGJDBIQR-UHFFFAOYSA-N
Quality Level	100
SMILES string	CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2cc3ccccc3c-4c2OP(O)(=O)Oc5c(cc6ccccc6c-45)-c7c(cc(cc7C(C)C)C(C)C)C(C)C
sustainability	Greener Alternative Product

Application:	Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas. Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Packaging:	100, 500 mg in glass bottle
Packaging:	Bottomless glass bottle. Contents are inside inserted fused cone.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97.0% (qNMR)
UNSPSC	12352005

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