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(R)-Ru(OAc)2(DM-SEGPHOS®)

ALDRICH/692182

Synonym: Diacetato[(R)-5,5′-bis[di(3,5-xylyl)phosphino]-4,4′-bi-1,3-benzodioxole]ruthenium(II)

Empirical Formula (Hill Notation): C50H50O8P2Ru
Molecular Weight: 941.94
MDL Number: MFCD09753025
Linear Formula: C50H50O8P2Ru
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-692182-50MG 50 mg
 $0.00
1/EA
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45-692182-100MG 100 mg
 $57.50
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form powder
functional group phosphine
InChI 1S/C46H44O4P2.2C2H4O2.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;2*1-2(3)4;/h9-24H,25-26H2,1-8H3;2*1H3,(H,3,4);/q;;;+2/p-2
InChI key ACKYBTAGKAINOG-UHFFFAOYSA-L
Quality Level 100 
SMILES string CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8
storage temp. 2-8°C
Application: Takasago Ligands and Complexes for Asymmetric Reactions 
Application: Catalyst for:
• Stereoselective preparation of β-amino amides via ruthenium segphos complex-catalyzed asymmetric reductive amination of β-keto amides
Legal Information: SEGPHOS is a registered trademark of Takasago Intl. Corp.
Legal Information: Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136
Packaging: 50, 100 mg in amber glass bottle
Storage Temp. 2-8°C
UNSPSC 12352005

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