RuCl₂[(R)−DM−BINAP][(R)−DAIPEN]

ALDRICH/692255

Synonym: Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(2R)−1,1−bis(4−methoxyphenyl)−3−methyl−1,2−butanediamine]ruthenium(II)

CAS Number: 220114-32-9
Empirical Formula (Hill Notation): C₇₁H₇₄Cl₂N₂O₂P₂Ru
Molecular Weight: 1221.28
Linear Formula: C₇₁H₇₄Cl₂N₂O₂P₂Ru
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-692255-100MG	100 mg	$64.90 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

form	powder
InChI	1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/t;18-;;;/m.1.../s1
InChI key	VMSNEARTLSFOHB-OEGAAENXSA-N
mp	197-211 °C
SMILES string	COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12
storage temp.	2-8°C

Application:	Takasago Ligands and Complexes for Asymmetric Reactions
Application:	Catalyst for: • Noyori-type enantioselective ketone hydrogenation • Enantioselective and asymmetric hydrogenation of ketones
Legal Information:	Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654
Packaging:	100 mg in glass insert
Packaging:	50 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	197-211 °C
Storage Temp.	2-8°C
UNSPSC	12352101

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