Synonym: Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(1R,2R)−1,2−diphenylethylenediamine]ruthenium(II)
CAS Number: 220114-38-5
Empirical Formula (Hill Notation): C66H64Cl2N2P2Ru
Molecular Weight: 1119.15
MDL Number: MFCD09753028
Linear Formula: C66H64Cl2N2P2Ru
Product Type: Chemical
| form |
powder |
| InChI |
1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1 |
| InChI key |
HYMSONXJNGZZBM-ODQAEMFESA-L |
| Quality Level |
100  |
| SMILES string |
Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10 |
| storage temp. |
2-8°C |
| Application: |
Takasago Ligands and Complexes for Asymmetric Reactions |
| Application: |
RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols. |
| General description: |
The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex. |
| Legal Information: |
Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654 |
| Packaging: |
50, 100 mg in amber glass bottle |
| RIDADR |
NONH for all modes of transport |
| WGK Germany |
WGK 3 |
| Flash Point(F) |
Not applicable |
| Flash Point(C) |
Not applicable |
| Storage Temp. |
2-8°C |
| UNSPSC |
12352005 |
