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Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate

ALDRICH/692573

Synonym: Bis(1,5-cyclooctadiene)rhodium BARF; Bis(1,5-cyclooctadiene)rhodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

CAS Number: 404573-66-6
Empirical Formula (Hill Notation): C48H36BF24Rh
Molecular Weight: 1182.48
MDL Number: MFCD10567026
Linear Formula: C48H36BF24Rh
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-692573-100MG 100 mg
 $188.00
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45-692573-500MG 500 mg
 $379.00
1/EA		 Add To Favorites

 

form solid
InChI 1S/C32H12BF24.2C8H12.Rh/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;2*1-2-4-6-8-7-5-3-1;/h1-12H;2*1-2,7-8H,3-6H2;/q-1;;;+1/b;2*2-1-,8-7-;
InChI key HQQAEXNVAYMZON-AUUWQFPRSA-N
mp 155-156 °C (D)
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string [Rh+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F
storage temp. −20°C
Application: Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate can be used as a catalyst for various transformations, including hydrogenation, intramolecular C-H alkenylation, cycloaddition of enynes, and reductive coupling reactions.
Packaging: 100, 500 mg in glass bottle
mp 155-156 °C (D)
Storage Temp. −20°C
UNSPSC 12161600

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