(S)-BINAP
ALDRICH/693057
Synonym: (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene; (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl; (S)-(−)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine); (S)-(−)-BINAP
CAS Number: 76189-56-5
Empirical Formula (Hill Notation): C44H32P2
Molecular Weight: 622.67
MDL Number: MFCD00010805
Linear Formula: [(C6H5)2PC10H6-]2
Product Type: Chemical
| form | crystals |
| InChI | 1S/C44H32P2/c1-5-19-35(20 |
| InChI key | MUALRAIOVNYAIW-UHFFFAOYSA |
| mp | 238-240 °C (lit.) |
| optical activity | [α]20/D -222, c = 0.5 in benzene |
| Application: | Takasago Ligands and Complexes for Asymmetric Reactions  |
| Application: | Reactant involved in: • Enantioselective and diastereoselective unpoled carbonyl allylation • Syntehsis of organophophine oxides as anittumor agents • SN2 halogenation of hydroxy groups • Synthesis of BINAP complexes • Studies of conformational flexibility of BINAP chelates |
| Legal Information: | Sold in collaboration with Takasago for research purposes only. |
| Packaging: | 100, 500 mg in amber glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| mp | 238-240 °C (lit.) |
| UNSPSC | 12352005 |