(S)-Ru(OAc)2(SEGPHOS®)
ALDRICH/693243
Synonym: Diacetato[(S)-(−)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II)
CAS Number: 373650-12-5
Empirical Formula (Hill Notation): C42H34O8P2Ru
Molecular Weight: 829.73
MDL Number: MFCD09753024
Linear Formula: C42H34O8P2Ru
Product Type: Chemical
form | powder |
InChI | 1S/C38H28O4P2.2C2H4O2.Ru/ |
InChI key | BHGLLIGZFQVMBJ-UHFFFAOYSA |
Quality Level | 100 |
storage temp. | 2-8°C |
Application: | (S)-Ru(OAc)2(SEGPHOS®) can be used as a catalyst: • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams. • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction. • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction. |
Application: | Takasago Ligands and Complexes for Asymmetric Reactions |
Legal Information: | SEGPHOS is a registered trademark of Takasago Intl. Corp. |
Legal Information: | Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 |
Packaging: | 50, 100 mg in amber glass bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Storage Temp. | 2-8°C |
UNSPSC | 12352005 |