Tris[2-phenylpyridinato-C2,N]iridium(III)
ALDRICH/694924 - sublimed grade
Synonym: Ir(ppy)3; Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
CAS Number: 94928-86-6
Empirical Formula (Hill Notation): C33H24IrN3
Molecular Weight: 654.78
MDL Number: MFCD12022527
Linear Formula: C33H24IrN3
Product Type: Chemical
λmax | 282 nm |
fluorescence | λex 305 nm; λem 507 nm in chloroform |
form | powder |
grade | sublimed grade |
InChI | 1S/3C11H8N.Ir/c3*1-2-6-10 |
InChI key | QKBWDYLFYVXTGE-UHFFFAOYSA |
loss | 0.5% loss on heating, 359°C (typical, TGA) |
OLED device performance | ITO/HMPD/TAZ:Ir(ppy)3 (7%)/Alq3/Al:Li • Color: green • Max. Luminance: 4000 Cd/m2 • Max. EQE: 15 % |
ITO/NPD/CBP:Ir(ppy)3 (6%)/Alq3/Mg:Ag • Color: green • Max. Luminance: 100000 Cd/m2 • Max. EQE: 8 % • Turn-On Voltage: 4.3 V |
|
ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al • Color: green • Max. Luminance: 207839 Cd/m2 • Max. EQE: 21.6 % • Turn-On Voltage: 2.1 V |
|
ITO/TCTA/Ir(ppy)3/Bphen/LiF/Al • Color: green • Max. Luminance: 300000 Cd/m2 • Max. EQE: 19 % • Turn-On Voltage: 2.6 V |
|
orbital energy | HOMO 5.6 eV |
LUMO 3 eV | |
SMILES string | c1ccc(nc1)-c2ccccc2[Ir](c |
transition temp | transition temp 437.6 °C (typical, DSC) |
Application: | OLED triplet emitter (green). |
Packaging: | 250 mg in glass insert |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
UNSPSC | 12352103 |