Bis(3,5-dimethylphenyl)phosphine

ALDRICH/695157

CAS Number: 71360-06-0
Empirical Formula (Hill Notation): C₁₆H₁₉P
Molecular Weight: 242.30
MDL Number: MFCD01074629
Linear Formula: C₁₆H₁₉P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-695157-500MG	500 mg	$258.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

density	1.017 g/mL at 25 °C
form	liquid
functional group	phosphine
InChI	1S/C16H19P/c1-11-5-12(2)8-15(7-11)17-16-9-13(3)6-14(4)10-16/h5-10,17H,1-4H3
InChI key	GPFIUEZTNRNFGD-UHFFFAOYSA-N
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
refractive index	n20/D 1.599
SMILES string	Cc1cc(C)cc(Pc2cc(C)cc(C)c2)c1

Application:	Bis(3,5-dimethylphenyl)phosphine can be used as a reactant to prepare: • Iron(II) chiral diimine diphosphine complexes as catalysts for the asymmetric transfer hydrogenation of ketones. • The complex of iridium with biphenol phosphite-phosphine bidentate ligand as an asymmetric catalyst for the hydrogenation of N-arylimines. • Chiral phosphines with excellent stereoselectivity by 1, 4 addition reaction with α,β-unsaturated aldehydes using a palladium catalyst.
Legal Information:	Product of Kanata Chemical Technologies, Inc.
Packaging:	100, 500 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302
Hazard Codes	Xn
Risk Statements	22
RIDADR	UN 3334
WGK Germany	WGK 3
Flash Point(F)	> 230.0 °F
Flash Point(C)	> 110 °C

Density	1.017 g/mL at 25 °C
Refractive Index	n20/D 1.599
UNSPSC	12352103

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