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1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane

ALDRICH/695459 - 97%

Synonym: 1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane; meCgPPh

CAS Number: 97739-46-3
Empirical Formula (Hill Notation): C16H21O3P
Molecular Weight: 292.31
Linear Formula: C16H21O3P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-695459-500MG 500 mg
 $123.00
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45-695459-2G 2 g
 $344.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 695459-2G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 695459-500MG

 

assay 97%
form solid
functional group phosphine
InChI 1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3
InChI key AVVSJWUWBATQBX-UHFFFAOYSA-N
mp 106-111 °C
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Cross Couplings
SMILES string CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2
Application: 1,3,5,7-Tetramethyl-6-phenyl-2,4,8-trioxa-6-phosphaadamantane can be used:
• As a ligand to synthesize complexes for hydroformylation catalysis.
• To catalyze the synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones and 3-methyl-3,4-dihydrocoumarins by intramolecular cyclocarbonylation.
Packaging: 2 g in glass bottle
Packaging: 500 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 106-111 °C
UNSPSC 12352005

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