1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene
ALDRICH/696188 - 97%
Synonym: 1,3-
CAS Number: 141556-42-5
Empirical Formula (Hill Notation): C21H24N2
Molecular Weight: 304.43
MDL Number: MFCD09265338
Linear Formula: C21H24N2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 696188-1G
| assay | 97% |
| form | powder |
| InChI | 1S/C21H24N2/c1-14-9-16(3) |
| InChI key | JCYWCSGERIELPG-UHFFFAOYSA |
| mp | 140 °C |
| reaction suitability | reagent type: catalyst |
| SMILES string | Cc1cc(C)c(N2[C]N(C=C2)c3c |
| storage temp. | −20°C |
| Application: | 1,3-Bis(2,4,6-trimethylph It can be used to synthesize: • IMes ligated-rhodium complex as a catalyst for the selective hydrogenation of substituted aryl and heteroaryl boronate esters to cis-substituted borylated cycloalkanes. • IMes/ruthenium complex (Cp*Ru(IMes)Cl)(Cp* =η5-C5Me3) as a catalyst for olefin ring closing metathesis reaction. IMes is also used as an ancillary ligand in Pd-catalyzed Suzuki-Miyaura cross-coupling reaction between aryl chlorides or aryl triflates and arylboronic acids. |
| Packaging: | 1 g in glass bottle |
| Packaging: | 250 mg in glass bottle |
| Symbol |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H228 - H315 - H319 - H335 |
| Precautionary statements | P210 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 26 |
| RIDADR | UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., H |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 140 °C |
| Storage Temp. | −20°C |
| UNSPSC | 12352005 |