Nickel(II) chloride ethylene glycol dimethyl ether complex
ALDRICH/696668 - 98%
Synonym: Dichloro(dimethoxyethane)
CAS Number: 29046-78-4
Empirical Formula (Hill Notation): C4H10O2 · Cl2Ni
Molecular Weight: 219.72
MDL Number: MFCD00013481
Linear Formula: NiCl2:CH3OCH2CH2OCH3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 696668-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 696668-5G
| assay | 98% |
| form | powder |
| InChI | 1S/C4H10O2.2ClH.Ni/c1-5-3 |
| InChI key | OCMNCWNTDDVHFK-UHFFFAOYSA |
| mp | >300 °C |
| Quality Level | 200  |
| reaction suitability | core: nickel |
| reagent type: catalyst | |
| SMILES string | Cl[Ni]Cl.COCCOC |
| Application: | Nickel(II) chloride ethylene glycol dimethyl ether complex can be used: • As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters. • As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds. • For the synthesis of nickel bis(benzimidazol-2-yliden • As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |     GHS02,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H261 - H301 - H315 - H319 - H334 - H350 - H400 |
| Precautionary statements | P231 + P232 - P273 - P301 + P310 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338 |
| Hazard Codes | T,N |
| Risk Statements | 45-25-36/38-43-50/53 |
| Safety Statements | 53-26-36/37-45-60-61 |
| RIDADR | UN 3134 6.1(4.3) / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | >300 °C |
| UNSPSC | 12161600 |