Titanium tetrachloride
ALDRICH/697079 - packaged for use in deposition systems
Synonym: Titanium(IV) chloride; TTC; Titanium tetrachloride
CAS Number: 7550-45-0
Empirical Formula (Hill Notation): Cl4Ti
Molecular Weight: 189.68
EC Number: 231-444-5
MDL Number: MFCD00011267
Linear Formula: TiCl4
Product Type: Chemical
Steel cylinder used to package pyrophoric substances for use in Atomic Layer Deposition systems.
| assay | ≥99.995% (trace metals analysis) |
| bp | 135-136 °C (lit.) |
| density | 1.73 g/mL at 20 °C (lit.) |
| form | liquid |
| InChI | 1S/4ClH.Ti/h4*1H;/q;;;;+4 |
| InChI key | XJDNKRIXUMDJCW-UHFFFAOYSA |
| mp | −25 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | core: titanium |
| reagent type: catalyst | |
| SMILES string | Cl[Ti](Cl)(Cl)Cl |
| vapor pressure | 50 mmHg ( 55 °C) |
| 9.6 mmHg ( 20 °C) |
| Application: | Titanium tetrachloride may be used in the vapor synthesis of titania powder by oxidaition. It may be used as a catalyst in cross and asymmetric aldol reactions. Other possible uses of titanium tetrachloride is in the synthesis of : • γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds, • N-Phosphinoylimines and N-sulphonylimines from aromatic aldehydes, • Homoallyl ethers from allylsilanes and acetals.6 |
| General description: | Atomic number of base material: 22 Titanium |
| Packaging: | 25 g in stainless steel cylinder |
| Symbol |   GHS05,GHS06 |
| Signal word | Danger |
| Hazard statements | H314 - H330 - H335 |
| Precautionary statements | P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 + P310 |
| Hazard Codes | T,C |
| Risk Statements | 14-23-34-39/23-48/23 |
| Safety Statements | 7/8-26-36/37/39-45 |
| RIDADR | UN 1838 8 |
| WGK Germany | WGK 1 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Supplemental Hazard Statements | EUH014 |
| Purity | ≥99.995% (trace metals analysis) |
| bp | 135-136 °C (lit.) |
| mp | −25 °C (lit.) |
| Density | 1.73 g/mL at 20 °C (lit.) |
| UNSPSC | 12352103 |