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[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

ALDRICH/697230

Synonym: Pd(dppf)Cl2

CAS Number: 72287-26-4
Empirical Formula (Hill Notation): C34H28Cl2FeP2Pd
Molecular Weight: 731.70
EC Number: 460-040-3
MDL Number: MFCD00015757
Linear Formula: (C17H14P)2Fe · PdCl2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-697230-1G 1 g
 $76.60
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45-697230-5G 5 g
 $234.00
1/EA		 Add To Favorites
45-697230-250G 250 g
 $9880.00
1/EA		 Add To Favorites
Pd(dppf)Cl2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 697230-250G

 

form powder
InChI 1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key JCWIWBWXCVGEAN-UHFFFAOYSA-L
mp 266-283 °C (lit.)
Quality Level 200 
reaction suitability core: palladium
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
SMILES string [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: Catalyst for C-C and C-N coupling reaction.
Application: Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
• Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
• Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
• Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
For small scale and high throughput uses, product is also available as ChemBeads (919780 )
Packaging: 1, 5, 250 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 266-283 °C (lit.)
UNSPSC 12161600

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