Copper(I) cyanide di(lithium chloride) complex solution
ALDRICH/697257 - in anhydrous tetrahydrofuran
Synonym: Copper(I) cyanide di(lithium chloride)
Empirical Formula (Hill Notation): CCl2CuLi2N
Molecular Weight: 174.35
Linear Formula: CuCN · 2LiCl
Product Type: Chemical
concentration | in anhydrous tetrahydrofuran |
density | 0.999 g/mL at 25 °C |
form | liquid |
InChI | 1S/CN.2ClH.Cu.2Li/c1-2;;; |
InChI key | QGXKBLXNBYNHBV-UHFFFAOYSA |
reaction suitability | core: copper |
reagent type: catalyst | |
SMILES string | [Li]Cl.[Li]Cl.[Cu]C#N |
Application: | Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc and Grignard reagents. It is also a useful precursor to prepare organocuprate(I) reagents. |
Packaging: | 50 mL in Sure/Seal™ |
Symbol | GHS02,GHS06,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H225 - H300 + H310 + H330 - H315 - H319 - H335 - H351 - H410 |
Precautionary statements | P210 - P260 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P304 + P340 + P310 |
Hazard Codes | F,T+,N |
Risk Statements | 11-19-26/27/28-32-36/37-40-50/53 |
Safety Statements | 16-26-28-36/37-45-61 |
RIDADR | UN 1992 6.1(3) / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | 1.4 °F - closed cup - Solve |
Flash Point(C) | -17 °C - closed cup - Solve |
Supplemental Hazard Statements | EUH018 - EUH019 |
Density | 0.999 g/mL at 25 °C |
UNSPSC | 12161600 |