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(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate

ALDRICH/697575

Synonym: JohnPhos Au(MeCN)SbF6

CAS Number: 866641-66-9
Empirical Formula (Hill Notation): C22H30AuF6NPSb
Molecular Weight: 772.17
MDL Number: MFCD11045449
Linear Formula: C22H30AuF6NPSb
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-697575-250MG 250 mg
 $149.00
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45-697575-1G 1 g
 $402.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 697575-1G

 

form solid
InChI 1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key ADQOZROJMVWPRI-UHFFFAOYSA-H
mp 198-203 °C (D)
Quality Level 100 
reaction suitability core: gold
  reagent type: catalyst
SMILES string [Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
Application: Gold Catalysts — 21st Century ′Gold Rush′ 
General description: (Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate is a phosphine ligated gold(I) complex. It is used as a catalyst in a domino reaction to form C–C, C–N, and C–O bonds due to the ease with which it can activate C=C and C≡C bonds, thus allowing for unique rearrangements or reactions with various nucleophiles. Gold catalysis provides an excellent method to construct complex chemical architectures in a mild manner that would be difficult to achieve using other reaction paradigms.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
mp 198-203 °C (D)
UNSPSC 12161600

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