Magnesium monoperoxyphthalate hexahydrate

ALDRICH/69868 - technical, ~80% (RT)

Synonym: Magnesium bis(monoperoxyphthalate) hexahydrate; MMPP

Empirical Formula (Hill Notation): C₁₆H₁₀MgO₁₀ · 6H₂O
Molecular Weight: 494.64
EC Number: 279-013-0
MDL Number: MFCD00149614
Linear Formula: (HO₂CC₆H₄CO₃)₂Mg·6H₂O
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-69868-50G	50 g	$74.40 1/EA		Add To Favorites
45-69868-250G	250 g	$182.00 1/EA		Add To Favorites
45-69868-1KG	1 kg	$580.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	~80% (RT)
form	powder
grade	technical
InChI	1S/2C8H6O5.Mg.6H2O/c29-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h21-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
InChI key	WWOYCMCZTZTIGU-UHFFFAOYSA-L
mp	93 °C (dec.) (lit.)
reaction suitability	reagent type: oxidant
SMILES string	O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO

Application:	Reagent for: • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst • Oxidation rections under mild conditions • Epoxidation of unsaturated steroids • Synthesis of ring-B oxygenated steroids as anticancer agents
General description:	Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.
Other Notes:	Versatile oxidant soluble in water and the lower alcohols.; Oxidations are carried out in homogenous solution (alcohol, aqueous alcohol) or in a two-phase system under PTC (chloroform-water)
Packaging:	1 kg in poly bottle
Packaging:	50, 250 g in poly bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H312 - H315 - H319 - H335
Precautionary statements	P280 - P302 + P352 + P312 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	~80% (RT)
mp	93 °C (dec.) (lit.)
UNSPSC	12352002

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