Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold

ALDRICH/699616

Synonym: [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride

CAS Number: 915299-24-0
Empirical Formula (Hill Notation): C₄₂H₆₃AuClO₃P
Molecular Weight: 879.34
MDL Number: MFCD11045473
Linear Formula: C₄₂H₆₃AuClO₃P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-699616-500MG	500 mg	$74.60 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	powder
InChI	1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1
InChI key	GCWCLHMEYZKZRO-UHFFFAOYSA-M
mp	200-202 °C
Quality Level	100
reaction suitability	core: gold
	reagent type: catalyst
SMILES string	Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C

Application:	Gold Catalysts — 21st Century ′Gold Rush′ • Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes
Application:	Catalyst for: • [4C+2C] cycloadditions • Cis-selective single-cleavagte skeletal cycloisomerization • Diastereoselective Au-catalyzed intermolecular cyclopropanation • Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes • Addition reactions
Packaging:	500 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	200-202 °C
UNSPSC	12161600

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