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(2-Butenyl)chloropalladium dimer

ALDRICH/700045 - ≥97%

Synonym: Bis[(1,2,3-η)-2-buten-1-yl]di-μ-chlorodi-palladiumdi-π-crotylpalladium chloride; Di-π-Crotylpalladium chloride; Di-2-butenyldipalladium dichloride; Dichlorobis(1-methylallyl)dipalladium

CAS Number: 12081-22-0
Empirical Formula (Hill Notation): C8H14Cl2Pd2
Molecular Weight: 393.94
MDL Number: MFCD01074457
Linear Formula: C8H14Cl2Pd2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-700045-1G 1 g
 $293.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 700045-1G

 

assay ≥97%
form powder
InChI 1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;
InChI key NTFUUQYNUUTALG-HYTOEPEZSA-L
mp 133-140 °C
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string CC=CC[Pd]Cl.CC=CC[Pd]Cl
Application: Catalyst for:
• Enantioselective elimination of palladium hydride
• Non-covalent anchoring of catalysts to silica supports
• Allylations of cyanoacetates
• Enantioselective nucleophilic substitutions

Reactant for:
• Allylic alkylation reactions
• Preparation of phosphane-functionalized carbosilane dendrimers
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Purity ≥97%
mp 133-140 °C
UNSPSC 12161600

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