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Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

ALDRICH/700223 - 97%

Synonym: Mn(dpm)3; Shenvi Hydrogenation Catalyst; Mn(TMHD)3; Tris(dipivaloylmethanato)manganese

CAS Number: 14324-99-3
Empirical Formula (Hill Notation): C33H57MnO6
Molecular Weight: 604.74
MDL Number: MFCD00269825
Linear Formula: Mn(C11H19O2)3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-700223-1G 1 g
 $59.90
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 700223-1G

 

assay 97%
form crystals
InChI 1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChI key ORZPLLPBZHORSD-LWTKGLMZSA-K
mp 160-170 °C
reaction suitability core: manganese
  reagent type: catalyst
SMILES string CC(C)(C)C(=O)C=C(/O[Mn](OC(=C/C(=O)C(C)(C)C)C(C)(C)C)OC(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
Application: Catalyst for:
• Intramolecular Diels-Alder reactions
• Single electron donor for excess electron transfer studies in DNA
• Enantioselective synthesis
• Borylation reactions
• Hydrohydrazination and hydroazidation
• Oxidative carbonylation of phenol
Application: Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol 
Packaging: 1 g in glass bottle
Purity 97%
mp 160-170 °C
UNSPSC 12161600

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