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(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

ALDRICH/700665

Synonym: (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

CAS Number: 864943-22-6
Empirical Formula (Hill Notation): C48H29O4P
Molecular Weight: 700.72
MDL Number: MFCD12546016
Linear Formula: C48H29O4P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-700665-100MG 100 mg
 $290.00
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form solid
functional group phosphate
InChI 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
InChI key BVICVEIKBNVROI-UHFFFAOYSA-N
mp 390-400 °C
optical activity [α]22/D −44.0°, c = 1 in DMSO
Quality Level 100 
SMILES string OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
storage temp. −20°C
Application: Catalyst for:
• Asymmetric hydrogenation cascade
• Enantioselective Friedel-Crafts reaction
• Asymmetric hydrogenation of 2-substituted quinolines
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
• Asymmetric transfer hydrogenation of substituted quinoxalines
Packaging: 100 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 390-400 °C
Storage Temp. −20°C
UNSPSC 12352005

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