[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

ALDRICH/701602 - 98%

Synonym: PdCl₂(dtbpf)

CAS Number: 95408-45-0
Empirical Formula (Hill Notation): C₂₆H₄₄Cl₂FeP₂Pd
Molecular Weight: 651.75
MDL Number: MFCD08064219
Linear Formula: C₂₆H₄₄Cl₂FeP₂Pd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-701602-250MG	250 mg	$127.00 1/EA	Add To Favorites
45-701602-1G	1 g	$276.00 1/EA	Add To Favorites
45-701602-5G	5 g	$1100.00 1/EA	Add To Favorites

PdCl₂(dtbpf)

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 701602-50G

12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
form	powder
greener alternative category	, Aligned
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/2C13H22P.2ClH.Fe.Pd/c21-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h27-10H,1-6H3;2*1H;;/q;;;;;+2/p-2
InChI key	JQZFOBWXNREQLO-UHFFFAOYSA-L
mp	203-208 °C
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst
SMILES string	[Fe].Cl[Pd]Cl.CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C
storage temp.	−20°C
sustainability	Greener Alternative Product

Application:	Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Application:	[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl₂(dtbpf)) may be used as catalyst in the Suzuki cross-coupling reaction of various aromatic and heteroaromatic halides with methyliminodiacetic acid derivatives (MIDA boronates) at room temperature (in the absence of organic solvent). It may be employed as catalyst for the synthesis of chalcones, via cross-coupling reactions.
Application:	[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) was used in the preparation of [PdCl₂(bisphosphinometallocene)] complexes. These complexes are reported to be the catalyst precursors for the Buchwald-Hartwig reaction. It is also employed as catalyst for greener Suzuki cross-coupling in TPGS-750-M. On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
General description:	[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) (PdCl₂(dtbpf)) participates as catalyst in Suzuki and Heck reactions. It is a preformed catalyst synthesized by a group of researchers at Johnson Matthey′s Catalysis and Chiral Technologies. It is an active catalyst for various Pd catalyzed cross-coupling reactions.
General description:	[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) is an air-stable, highly active and versatile catalyst. It is an efficient catalyst for cross-coupling reactions. It participates as catalyst in various coupling reactions of the fine chemicals and pharmaceutical chemicals. It is commonly employed as homogeneous catalyst in the Suzuki reactions. PdCl2(dtbpf) is an air-stable cross-coupling catalyst used in the Suzuki coupling of various aryl chlorides.
Packaging:	1, 5, 50 g in glass bottle
Packaging:	15 mg in ampule
Packaging:	250 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	203-208 °C
Storage Temp.	−20°C
UNSPSC	12161600

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