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[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II)

ALDRICH/701998 - 98%

Synonym: PdCl2(dcypf)

CAS Number: 917511-90-1
Empirical Formula (Hill Notation): C34H52Cl2FeP2Pd
Molecular Weight: 755.90
MDL Number: MFCD11656081
Linear Formula: C34H52Cl2FeP2Pd
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-701998-250MG 250 mg
 $59.00
1/EA		 Add To Favorites
45-701998-1G 1 g
 $224.00
1/EA		 Add To Favorites

 

assay 98%
form powder
InChI 1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2
InChI key HRAMBTUEZQOQRK-UHFFFAOYSA-L
mp 294-300 °C
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string [Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(C2CCCCC2)C3CCCCC3.[CH]4[CH][CH][C]([CH]4)P(C5CCCCC5)C6CCCCC6
storage temp. −20°C
Application: 1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of:
• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids.
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 98%
mp 294-300 °C
Storage Temp. −20°C
UNSPSC 12161600

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