Lanthanum(III) chloride bis(lithium chloride) complex solution
ALDRICH/703559 - 0.6 M in THF
Synonym: Lanthanum trichloride lithium chloride complex
CAS Number: 405204-22-0
Empirical Formula (Hill Notation): Cl5LaLi2
Molecular Weight: 330.05
Linear Formula: LaCl3 · 2LiCl
Product Type: Chemical
concentration | 0.6 M in THF |
16 % (w/w) | |
density | 1.05 g/mL at 25 °C |
form | liquid |
InChI | 1S/5ClH.La.2Li/h5*1H;;;/q |
InChI key | YSKOYVQYUJUXCN-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | reagent type: catalyst core: lanthanum |
SMILES string | [Li]Cl.[Li]Cl.Cl[La](Cl)C |
Application: | Selective 1,2-Additions with LaCl3•2LiCl • Mediates Grignard additions • Reagent for metal exchange reactions • Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines |
Legal Information: | Product of Albemarle US Inc |
Packaging: | 25, 4×25, 100 mL in Sure/Seal™ |
Symbol | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H225 - H290 - H302 - H317 - H318 - H335 - H336 - H351 - H412 |
Precautionary statements | P210 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313 |
Hazard Codes | F,Xn |
Risk Statements | 11-19-36/37/38-40 |
Safety Statements | 16-26-36/37 |
RIDADR | UN 2056 3 / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | 62.6 °F |
Flash Point(C) | 17 °C |
Supplemental Hazard Statements | EUH019 |
Density | 1.05 g/mL at 25 °C |
UNSPSC | 12352106 |