RuCl(p-cymene)[(R,R)-Ts-DPEN]

ALDRICH/703907

Synonym: [N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium

CAS Number: 192139-92-7
Empirical Formula (Hill Notation): C₃₁H₃₅ClN₂O₂RuS
Molecular Weight: 636.21
MDL Number: MFCD10567385
Linear Formula: C₃₁H₃₅ClN₂O₂RuS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-703907-100MG	100 mg	$29.10 1/EA	Add To Favorites
45-703907-500MG	500 mg	$105.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	powder
InChI	1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key	AZFNGPAYDKGCRB-AGEKDOICSA-M
mp	215 °C
optical activity	[α]20/D −116°, c = 0.1 in chloroform
SMILES string	CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
storage temp.	2-8°C

Application:	Takasago Ligands and Complexes for Asymmetric Reactions
Application:	Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of: • Quinolines • N-Alkyl ketimines • Antitumor and antiproliferative derivatives of natural products isolated from bacteria • Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation Catalyst with improved performance modified via microenvironment engineering of nanocages
General description:	RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.
Legal Information:	Sold in collaboration with Takasago for research purposes only. WO9720789
Packaging:	100 mg in clear glass bottle
Packaging:	500 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	215 °C
Storage Temp.	2-8°C
UNSPSC	12352116

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