RuCl(p-cymene)[(S,S)-Ts-DPEN]

ALDRICH/703915

Synonym: [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium

CAS Number: 192139-90-5
Empirical Formula (Hill Notation): C₃₁H₃₅ClN₂O₂RuS
Molecular Weight: 636.21
MDL Number: MFCD14155881
Linear Formula: C₃₁H₃₅ClN₂O₂RuS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-703915-100MG	100 mg	$49.80 1/EA	Add To Favorites
45-703915-500MG	500 mg	$140.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
InChI key	AZFNGPAYDKGCRB-XCPIVNJJSA-M
mp	>175 °C
optical activity	[α]20/D +178°, c = 0.5 in chloroform
SMILES string	CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
storage temp.	2-8°C

Application:	Takasago Ligands and Complexes for Asymmetric Reactions
Application:	Catalyst involved in: • Asymmetric transfer hydrogenation of imines and ketones • Intramolecular asymmetric reductive amination • Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes
General description:	RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.
Legal Information:	Sold in collaboration with Takasago for research purposes only. WO9720789
Packaging:	100 mg in clear glass bottle
Packaging:	500 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	>175 °C
Storage Temp.	2-8°C
UNSPSC	12352116

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