R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η₄-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

ALDRICH/704628 - 96%

Synonym: (R)-TCFP-Rh; TCFP; R-[Rh cod TCFP]BF₄

Empirical Formula (Hill Notation): C₂₂H₄₄P₂Rh
Molecular Weight: 473.44
MDL Number: MFCD11973806
Linear Formula: C₂₂H₄₄P₂Rh
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-704628-100MG	100 mg	$406.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	96%
form	solid
functional group	phosphine
InChI	1S/C14H32P2.C8H12.BF4.Rh/c1-12(2,3)15(10)11-16(13(4,5)6)14(7,8)9;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11H2,1-10H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t15-;;;/m1.../s1
InChI key	CQCAQRWECWCUBU-JMJDVLNDSA-N
mp	171-177 °C
Quality Level	100
SMILES string	[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CP(CP(C(C)(C)C)C(C)(C)C)C(C)(C)C
storage temp.	2-8°C

Application:	R-(tert-Butylmethylphosphino-di-tert-butylphosphinomethane)-η4-(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can be used: • In the asymmetric reduction of amines, ketones and unsaturated acids. • As a hydrogenation catalyst in the preparation of diastereomers of trifluorovaline. • As a catalyst in the olefin asymmetric hydrogenation.
Legal Information:	Sold in collaboration with Johnson Matthey for research purposes only.
Packaging:	100 mg in clear glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 2
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	96%
mp	171-177 °C
Storage Temp.	2-8°C
UNSPSC	12352002

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